Evaluation of ch4 emission in two paddy field areas, Khonkaen and Ayutthaya, in Thailand

Abstract

It is well known that submerged soils emit high levels of methane (CH4 ) due to oxygen deprivation and free iron oxide causing a quick reduction. However, there are other soil properties that control the reduction processes in soil, especially the amount of soil organic carbon (SOC). This study aimed to investigate the major factors controlling CH4 production potential (CH4 PP) in Thai paddy fields. Two provinces, Ayutthaya, a clay soil region, and Khonkaen, a sandy soil region, were selected to represent a wide range of soil textures. Soil characteristic analysis pre-and post-incubation, and weekly gas detection in an incubation experiment over two months, was conducted. Stepwise multiple regression analysis was employed to analyze major soil factors controlling CH4 PP. For the regional prediction of CH4 PP, a map dataset of Ayutthaya and Khonkaen by the Land Development Department, Thailand, and a soil texture map (with intersected point data using the soil property map in ArcGIS) by OpenLandMap, were used. CH4 PP was correlated with 1:10 pH, Fe2+, and water-soluble organic carbon (WSOC) measured after incubation. Although CH4 PP showed no significant correlation with any soil properties measured before incubation, CH4 PP was correlated with SOC, 1:10 electrical conductivity (EC), exchangeable ammonium (ExNH4 ), and sand content. It was thought that SOC and ExNH4 were related to organic matter decomposition, 1:10 EC was related to SO42− reduction and sand content was related to free oxides. Predicted regional CH4 PP was similar in Ayutthaya and Khonkaen, although SOC, ExNH4 and 1:10 EC was higher, and sand content was lower in Ayutthaya than in Khonkaen. In both regions, the distribution of CH4 PP corresponded to SOC, and CH4 PP was lower with lower sand content and higher 1:10 EC. In clayey Ayutthaya, higher CH4 PP was observed in the area with higher ExNH4 . This indicates that soil properties other than soil texture and SOC influence CH4 PP in the paddy fields in Thailand.