Studies focusing on the functionalization of the surface of free silicon nanoparticles are presented. This functionalization is applied to hydrogen-terminated silicon nanoparticles to evaluate how far the well-known solution-phase chemistry of thermal-, radical-, Lewis acid- and UV light-mediated hydrosilylation can be applied to the surface chemistry of silicon nanoparticles. The efficiencies of hydrosilylation for thermal-, radical- and Lewis acid-mediated reactions on silicon nanoparticles surfaces, deduced from the intensity of the √(Si-H) absorption, are found to be comparable. © Springer-Verlag 2007.
CITATION STYLE
Nelles, J., Sendor, D., Ebbers, A., Petrat, F. M., Wiggers, H., Schulz, C., & Simon, U. (2007). Functionalization of silicon nanoparticles via hydrosilylation with 1-alkenes. Colloid and Polymer Science, 285(7), 729–736. https://doi.org/10.1007/s00396-006-1622-4
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