This paper investigates Cassia fistula leaf-extract effects on the inhibition of stainless-steel corrosion in 0.5 M HCl. Measurements of corrosion rate were obtained through linear sweep voltammetry (LSV) technique, at the ambient temperature of 28 °C from stainless-steel specimens immersed in the acidic medium, containing different Cassia fistula leaf-extract concentrations. Results showed that inhibition effectiveness on stainless-steel corrosion increases with increasing concentration of the leaf-extract. The 10 g/L Cassia fistula leaf-extract, the highest concentration of the leaf-extract employed in the study, exhibited optimal inhibition efficiency η = 88.46% on the corrosion of the stainless-steel metal. Adsorption isotherm modelling shows that the experimental data followed the Flory-Huggins isotherm with excellent model efficiency, r2 = 90.27%, and the Langmuir model with very good model efficiency, r2 = 78.83%. Other isotherm parameters indicate favourable adsorption and suggest physisorption as the prevalent mechanism of corrosion protection by the leaf-extract on stainless-steel in the acidic chloride environment.
CITATION STYLE
Omotosho, O. A., Okeniyi, J. O., Loto, C. A., Popoola, A. P. I., Ajibola, O. B., & Ogbiye, A. S. (2017). Cassia fistula leaf-extract effect on corrosion-inhibition of stainless-steel in 0.5 M HCl. In Minerals, Metals and Materials Series (pp. 179–189). Springer International Publishing. https://doi.org/10.1007/978-3-319-52132-9_18
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