"Chemical Equation Presented" Radical changes: One single P-Rh-P angle determines whether the odd electron in the paramagnetic complex [Rh(trop2PPh)(PPh3)] is delocalized over the whole molecule (see picture, blue) or is localized on the P - Rh unit (red). The two energetically almost degenerate electromers exist in a fast equilibrium, and the "red" complex has the highest spin density at Rh of all low valent Rh complexes observed to date. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
CITATION STYLE
Puschmann, F. F., Harmer, J., Stein, D., Rüegger, H., De Bruin, B., & Grützmacher, H. (2010). Electromeric rhodium radical complexes. Angewandte Chemie - International Edition, 49(2), 385–389. https://doi.org/10.1002/anie.200903201
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