A Highly Stable Organic Luminescent Diradical

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Abstract

It is very challenging to obtain stable room-temperature luminescent open-shell singlet diradicals. Herein we report the first stable Müller's hydrocarbon TTM-PhTTM with luminescent properties. Variable-temperature electron paramagnetic resonance spectroscopy measurements and theoretical calculations show that TTM-PhTTM has an open-shell singlet ground state with a diradical character of 90 %. Because of a small singlet-triplet energy gap, the open-shell singlet ground state can be thermally excited to a triplet state. TTM-PhTTM shows room-temperature deep-red emission in various solutions. Unusually high stability of TTM-PhTTM was also observed owing to effective steric hindrance and spin delocalization. Our results are beneficial to the rational design and discovery of more stable luminescent diradical materials.

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Abdurahman, A., Wang, J., Zhao, Y., Li, P., Shen, L., & Peng, Q. (2023). A Highly Stable Organic Luminescent Diradical. Angewandte Chemie - International Edition, 62(15). https://doi.org/10.1002/anie.202300772

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