Pomegranate arils extract as a green corrosion inhibitor for mild steel: effect of concentration and temperature in hydrochloric acid

Abstract

Corrosion inhibitors generated from plants and organic compounds are critical for achieving a greener environment. In this work we investigated the corrosion inhibition of pomegranate arils extract (PAE) for mild steel in 1M HCl by potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), and profilometry measurements. The effects of PAE concentration (100, 200, 400 mg l-1) and temperature (298, 313, and 333 K) on the PAE inhibition efficiency were evaluated. Polarization measurements revealed that PAE was a mixed anodic-cathodic inhibitor. Corrosion inhibition efficiency was around 74% at a PAE concentration of 400 mg l-1 at 298K. However, at 333 K, the corrosion current density in the solution containing 400 mg l-1 of PAE was measured to be 1.28 mA cm−2, which was higher than that in the blank solution (0.92 mA cm−2). This increase in corrosion rate at 333 K demonstrates the negative influence of high temperatures on PAE inhibition efficiency. The PAE green inhibitor was discovered to have a physical adsorption characteristic and to obey the Langmuir adsorption isotherm.