Abstract
Hot and bothered? Frustrated Lewis pairs comprising phosphine and borane react to reversibly bind and release CO2, offering a rare example of metal-free CO2 sequestration. The mechanism of formation of these CO2 derivatives 1 and 2 (see scheme) by almost simultaneous P - C and O - B bond formation was characterized by quantum chemical calculations. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.
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Mömming, C. M., Otten, E., Kehr, G., Fröhlich, R., Grimme, S., Stephan, D. W., & Erker, G. (2009). Reversible metal-free carbon dioxide binding by frustrated lewis pairs. Angewandte Chemie - International Edition, 48(36), 6643–6646. https://doi.org/10.1002/anie.200901636
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