A thermodynamic study of arsenic adsorption onto iron species generated by electrocoagulation

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Abstract

The present study evaluated the feasibility of using iron species generated by electrocoagulation (EC) as an adsorbent for removal As(III/As(V) from aqueous media. The full potential of EC was evident in that more than 99 percent of arsenic was removed without addition of chemical reagents. The adsorbent iron-species generated by EC was characterized by Chemical Analyses, X-Ray Diffraction and Scanning Electron Microscopy. The experimental data were correlated by employing a Langmuir adsorption isotherm. Thermodynamic parameters such as ΔH°, ΔS° and ΔG° were calculated. The adsorption process was found to be exothermic and spontaneous.

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Parga, J. R., De Los Santos, A., & Valenzuela, J. L. (2008). A thermodynamic study of arsenic adsorption onto iron species generated by electrocoagulation. In Proceedings of the 2008 Global Symposium on Recycling, Waste Treatment and Clean Technology, REWAS 2008 (pp. 199–206).

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