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2,7-Diazabicyclo[2.2.1]heptanes: Novel asymmetric access and controlled bridge-opening

Chemical Communications (2019) 55(29) 4214-4217
DOI: 10.1039/c8cc10263e
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Abstract

Organocatalysed asymmetric Michael additions of substituted triketopiperazines to enones afford products in high yield and enantiomeric ratio (er). Further modification delivers products possessing natural product (NP) scaffolds including diazabicyclo[2.2.1]heptane, prolinamide and harmicine.

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APA

Peczkowski, G. R., Craven, P. G. E., Stead, D., & Simpkins, N. S. (2019). 2,7-Diazabicyclo[2.2.1]heptanes: Novel asymmetric access and controlled bridge-opening. Chemical Communications, 55(29), 4214–4217. https://doi.org/10.1039/c8cc10263e

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