Tetrakis[bis(pyridin-2-yl)amine-κN2](nitrato-κO) silver(I)

Abstract

In the title complex, [Ag(NO3)(C10H9N3)4], the nitrate ligand is found to be disordered over two sets of positions, with occupancy factors of 0.473(5) and 0.527(5). The AgI ion is located in a square-pyramidal coordination environment formed by four N atoms from four bis(pyridin-2-yl)amine ligands and one O atom from a nitrate ligand. Weak interactions between the AgI ions and the nitrate anions acting in a monodentate mode [AgO = 2.791(13) and 2.816(9)Å for the major component of the nitrate ligand, and 2.865(8) and 2.837(8)Å for the minor component] link the complex molecules into a chain along [001]. N - HO hydrogen bonds are observed. © Parashchenko et al. 2014.