Equilibrium and kinetics of nitrate removal by protonated cross-linked chitosan

Abstract

Nitrate, contained in surface or groundwater, can be removed by sorption on protonated cross-linked chitosan gel beads. The sorption capacity is pH-dependent and large enough to meet the standard of drinkable water. The isothermal equilibrium curves are straight lines, which implies that the removal is independent of the initial concentration. The main reactive process, Which probably depends on the secondary ammonium groups, involves the total bead volume and not only its surface. If required, the sorption capacity is easily recovered by increasing the pH to 12. The main competitor is fluoride but, even in its presence, the sorption capacity of nitrate remains significant. The sorption kinetics, which can be represented by a mass transfer equation, is not limited by pore or by film diffusion.