The Preparation of Photocatalytic Porous Magnesium Oxychloride Cement-Based Materials and Its De-NOx Performance

Abstract

Porous magnesium oxychloride cement (PMOC) has a high specific surface area formed by interlocking whiskers, which can be used as a promising photocatalyst substrate for the photocatalytic removal of atmospheric pollutants. In this paper, magnesium oxychloride cement (MOC) was used as matrix and TiO2 as catalyst to prepare MOC blocks. Plant-based protein was used as a foaming agent to form the layered porous structure suitable for supporting TiO2 particles, which effectively increased the surface area of light radiation and TiO2 adhesion area in photocatalytic porous magnesium oxychloride cement (PPMOC). It was found that the addition of the foaming agent can increase the adsorption capacity of MOC to TiO2. The vacuum-immersion loading method can effectively support TiO2 on the surface of PMOC. The photocatalytic performance of PPMOC can be improved by multiple loading, while higher porosity of PMOC would reduce the loading surface of matrix to TiO2 particles, which might decrease the photocatalytic efficiency. As can be observed in PPMOC specimens, when the porosity of PPMOC is less than 60%, increasing the porosity can improve the photocatalytic efficiency, while when the porosity is higher than 60%, increasing the porosity decreased the photocatalytic efficiency due to the reduction of the loading surface. The excellent nitrate selectivity of PPMOC also shows good application potential in the field of catalytic degradation of nitrogen oxides.