Ultrafast extended x-ray absorption fine structure (EXAFS) - Theoretical considerations

Abstract

Inspired by the recent experimental demonstration of ultrafast x-ray absorption spectroscopy, we present a framework for the calculation of extended x-ray absorption fine structure (EXAFS) spectra on the ultrafast (femtosecond to picosecond) time scale. Model calculations for gas phase I2, evolving under the influence of laser pumping, demonstrate that ultrafast EXAFS has the potential to serve as a direct probe of nuclear dynamics, including time-dependent interatomic separations and relative orientations. The feasibility of ultrafast EXAFS as a viable and useful experimental technique is discussed. © 1999 American Institute of Physics.