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Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy

Springer Science and Business Media Deutschland GmbH, (2009), 307-309
DOI: 10.1007/978-3-540-95946-5_99
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Abstract

We studied the vibrational structure of reactive S1 cis-stilbene through wavepacket motions generated impulsively at various delay-times. They showed gradual frequency downshift, demonstrating highly anharmonic nature of the excited-state potential and structural evolution with photoisomerization.

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Takeuchi, S., Ruhman, S., Tsuneda, T., Chiba, M., Taketsugu, T., & Tahara, T. (2009). Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy. In Springer Series in Chemical Physics (Vol. 92, pp. 307–309). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_99

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