An electrostatic lens for focusing charged particles in a mass spectrometer

Abstract

The ability to transmit particles into the ablation region of an aerosol mass spectrometer determines in part the lower size limit for particles that can be analyzed. A large fraction of small particles (< 100 nm) are lost due to processes such as Brownian diffusion that broaden the particle beam. In this work, electrostatic focusing is used to overcome the limits of aerodynamic focusing in the analysis of nanometer-sized particles by aerosol mass spectrometry. A simple tube lens is used to focus charged particles into the ablation laser beam path. The diameter of the focused beam is smaller than the fundamental aerodynamic limit imposed by Brownian motion. Measured enhancements of the hit rate for particles between 21 and 33 nm diameter are between 3 and 6. These values are lower limits for the true enhancements. The lens is also energy selective and can be used to select the mass (size) of the particles being analyzed.