Abstract
Tapered (cone-shaped) bottlebrush polymers were synthesized for the first time by ring-opening metathesis polymerization (ROMP) using a sequential-addition of macromonomers (SAM) strategy. Polystyrene macromonomers with molecular weights that increased from 1 to 10 kg mol-1 were polymerized in sequence to high conversion, yielding tapered bottlebrush polymers that could be visualized by atomic force microscopy (AFM).
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CITATION STYLE
Radzinski, S. C., Foster, J. C., Scannelli, S. J., Weaver, J. R., Arrington, K. J., & Matson, J. B. (2017). Tapered Bottlebrush Polymers: Cone-Shaped Nanostructures by Sequential Addition of Macromonomers. ACS Macro Letters, 6(10), 1175–1179. https://doi.org/10.1021/acsmacrolett.7b00724
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