Toxic elements (As, Se, Cd, Hg, Pb) and their mineral and technogenic formations in the snow cover in the vicinity of the industrial enterprises of Tomsk

Abstract

Snow samples were collected in four industrial areas of Tomsk where brickworks, factories for the production of reinforced concrete structures, machine repair industries and local boilers, petrochemical plant and thermal power station are located. Study of insoluble fraction of aerosols in snow and melted snow water was performed to determine the contents of the emissions from these facilities. The insoluble fraction of aerosols in snow is aerosol particles deposited on snow cover. As, Se, Cd, Hg, Pb concentration was analyzed by inductively coupled plasma mass spectrometry (ICP-MS). Mineral modes of the elements were determined by scanning electron microscope. It was found the snow cover is mainly polluted by As, Se, Cd, Hg, Pb in the thermal power station impact area, by As - in the brickworks impact area, by Se - in the impact area of densely located factories for the production of reinforced concrete structures, machine repair industries and local boilers. The research results show that the mineral modes of As are associated with arsenopyrite, of Pb - with galena in the insoluble fraction of aerosols in snow.