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Selective formation of formamidines or 7-aminomethylbenzoxazoles from unprecedented couplings between benzoxazoles and amines

Advanced Synthesis and Catalysis (2012) 354(9) 1672-1678
DOI: 10.1002/adsc.201100521
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Abstract

A method for the selective synthesis of amidines by ring-opening amination or of 7-aminomethylbenzoxazoles via a novel three-component-coupling reaction (arene, dichloromethane and amine) from benzoxazoles and amines was developed. Amidines could be further converted into 2-aminobenzoxazoles in high yield. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Yu, D., Lee, S., Sum, Y. N., & Zhang, Y. (2012). Selective formation of formamidines or 7-aminomethylbenzoxazoles from unprecedented couplings between benzoxazoles and amines. Advanced Synthesis and Catalysis, 354(9), 1672–1678. https://doi.org/10.1002/adsc.201100521

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