Side-chain effects on friction-transferred polymer orientation

Abstract

Effects of substituted side-chains of poly(2,5-dialkoxy-1,4- phenylenevinylene) derivatives (PPV) on polymer orientation have been studied using polarized optical spectroscopy and synchrotron-sourced grazing incidence X-ray diffraction (GIXD) analysis. The results of polarized optical spectroscopy indicate that the symmetrically substituted PPV is suitable for homogeneous oriented film preparation by friction-transfer technique. The formed film of poly(2,5-(2-ethylhexyloxy)-1,4-phenylenevinylene) (BEHPPV) exhibited large light emission dichroism of up to 42.0. The results of synchrotron-sourced GIXD for BEHPPV film indicated that the BEHPPV molecules crystallized in not a different manner from that of other PPV. © 2007 The Society of Polymer Science.