Microcrystalline-silicon-oxide-based N-type reflector structure in micromorph tandem solar cells

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Abstract

N-type microcrystalline silicon oxide thin films (n-μc-SiO x:H) have been deposited by VHF-PECVD (40MHz) with reactant gas mixtures of CO2/SiH4 and H2. N-c-SiOx thin films exhibiting low refractive index value (n 600nm ∼2), and medium/high conductivity (> 10-9 S/cm) are suitable to be used as an n-type reflector in micromorph tandem solar cells. Transmission electron microscopy (TEM) results show that microstructures of n-c-SiOx:H thin films contain nanocrystalline Si particles, which are randomly embedded in the a-SiOx matrix. This specific microstructure provides n-c-SiO x:H thin films excellent optoelectronic properties; therefore, n- c-SiOx:H thin films are appropriate candidates for n-type reflector structures in Si tandem solar cells. Copyright © 2012 Chiung-Nan Li et al.

Figures

  • Figure 1: a-Si/μc-Si micromorph tandem solar cells with an intermediate reflector structure (IRS) or a “n-type reflector” structure (NRS) by incorporating specific n-μc-SiOx :H thin films.
  • Figure 2: Raman spectra of n-μc-SiOx :H thin films deposited with R = 8 ∼ 20 under different hydrogen dilution.
  • Figure 3: Physical properties of n-μc-SiOx :H thin films (thickness = 40∼50 nm) with R = 8∼20 under [H2] = 600 sccm (filled symbols) and 900 sccm (open symbols). (Δ, and : refractive index, n; , and : crystallinity; ◦, and •: dark conductivity).
  • Figure 4: TEM bright field images (a) and dark field images (b) of n-μc-SiOx :H thin films deposited on glass substrates (100KX). The dark field image is taken by the Si (111) diffraction (c); TEM bright field images of a-Si/μc-Si tandem cells (25 KX); (d) HRTEM images of the N-reflector (n-μc-SiOx thin films, 800KX).
  • Table 1: I-V parameters of a-Si/μc-Si tandem cells (300 nm/3 μm) with “Standard structure,” IRS, and NRS. JTOP and JBTM are obtained from EQE analyses, as shown in Figure 4.
  • Figure 5: Quantum efficiency of a-Si top cells and μc-Si bottom cells in three types of micromorph cells (Std., IRS, and NRS).

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Li, C. N., Fang, H. Y., Chen, Y. H., Yeh, C. M., Huang, C. F., Wang, Y. C., … Chen, C. H. (2012). Microcrystalline-silicon-oxide-based N-type reflector structure in micromorph tandem solar cells. International Journal of Photoenergy, 2012. https://doi.org/10.1155/2012/513238

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