Abstract
Electron(ic) banking: First-row transition metals can be given a noble character by redox-active ligands, thus enabling two-electron oxidative addition and reductive elimination steps (see scheme). A recently reported cobalt-mediated Negishi-type cross-coupling reaction provides an illustrative example of this concept and reveals its potential to develop new catalytic reactions with cheap, abundant metals. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Dzik, W. I., Van Der Vlugt, J. I., Reek, J. N. H., & De Bruin, B. (2011). Ligands that store and release electrons during catalysis. Angewandte Chemie - International Edition, 50(15), 3356–3358. https://doi.org/10.1002/anie.201006778
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