Laboratory and Astronomical Discovery of Magnesium Dicarbide, MgC 2

  • Changala P
  • Gupta H
  • Cernicharo J
  • et al.
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Abstract

We report the detection of magnesium dicarbide, MgC 2 , in the laboratory at centimeter wavelengths and assign 24 MgC 2 , 25 MgC 2 , and 26 MgC 2 to 14 unidentified lines in the radio spectrum of the circumstellar envelope of the evolved carbon star IRC+10216. The structure of MgC 2 is found to be T-shaped with a highly ionic bond between the metal atom and the C 2 unit, analogous to other dicarbides containing electropositive elements. A two-temperature excitation model of the MgC 2 emission lines observed in IRC+10216 yields a very low rotational temperature of 6 ± 1 K, a kinetic temperature of 22 ± 13 K, and a column density of (1.0 ± 0.3) × 10 12 cm −2 . The abundance of MgC 2 relative to the magnesium–carbon chains MgCCH, MgC 4 H, and MgC 6 H is 1:2:22:20 and provides a new constraint on the sequential radiative association–dissociative recombination mechanisms implicated in the production of metal-bearing molecules in circumstellar environments.

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Changala, P. B., Gupta, H., Cernicharo, J., Pardo, J. R., Agúndez, M., Cabezas, C., … McCarthy, M. C. (2022). Laboratory and Astronomical Discovery of Magnesium Dicarbide, MgC 2. The Astrophysical Journal Letters, 940(2), L42. https://doi.org/10.3847/2041-8213/aca144

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