Abstract
A permanently porous, three-dimensional metal-organic material formed from zero-valent metal nodes is presented. Combination of ditopic m-terphenyl diisocyanide, [CNArMes2]2, and the d10 Ni(0) precursor Ni(COD)2, produces a porous metal-organic material featuring tetrahedral [Ni(CNArMes2)4]n structural sites. X-ray absorption spectroscopy provides firm evidence for the presence of Ni(0) centers, whereas gas-sorption and thermogravimetric analysis reveal the characteristics of a robust network with a microdomain N2-adsorption profile.
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CITATION STYLE
Agnew, D. W., Dimucci, I. M., Arroyave, A., Gembicky, M., Moore, C. E., MacMillan, S. N., … Figueroa, J. S. (2017). Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides. Journal of the American Chemical Society, 139(48), 17257–17260. https://doi.org/10.1021/jacs.7b09569
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