Formula of compressibility and using it for air, noble gases, some hydrocarbons gases, some diatomic simple gases and some other fluids

Abstract

Based on solutions of the Ornstein-Zernike equation (OZE) of Lennard-Jones potential for mean spherical approximation (MSA), we derive analytical formula for the compressibility assuming that the system is of low density, homogeneous, isotropic and composed of one component. Depending on this formula, we find the values of the bulk modulus and the compressibility of air at room temperature and the bulk modulus and the compressibility of Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbon. Also, we find the speed of sound in the air at various temperatures, the speed of sound in each of Helium, Neon, Argon, Krypton, Xenon, Methane, Ethylene, Propylene, Propane, Hydrogen, Nitrogen, Fluorine, Chlorine, Oxygen, Nitrous oxide (laughing gas), Carbon dioxide, Nitric oxide, Carbon monoxide, Sulphur dioxide and dichlorodifluoromethane at room temperature. Besides, we find the speed of sound in Methane, Ethylene, Propylene and Propane at nine per ten of critical temperature of each hydrocarbons depending on the formula we find. We show that the simple formula we derive in this work is reliable and agrees with the results obtained from other studies and literatures. We believe it can be used for many systems which are in low densities and described by Lennard-Jones potential. [Figure not available: see fulltext.].