Abstract
The reaction of tributylphosphine with the catalytic system (C5H5)2 TiCl2-LiC4H9 prepared in an atmosphere of H2 has been investigated in toluene solution. By using the ESR technique, a hydride complex Cp2Ti(H) (PBu3) has been detected. The proportionality between the rate of cyclohexene hydrogenation and the complex concentration has been established. The kinetics of cyclohexene hydrogenation has been investigated and a reaction mechanism is proposed. © 1976 Akadémiai Kiadó.
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CITATION STYLE
Shmidt, F. A., Ryntina, N. M., Saraev, V. V., Gruznykh, V. A., & Makarov, V. A. (1976). Nature of the activity and the kinetics of cyclohexene hydrogenation by the catalytic system (C5H5)2 TiCl2-LiC4H9. Reaction Kinetics and Catalysis Letters, 5(2), 101–106. https://doi.org/10.1007/BF02279775
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