Water Soluble Self-Aggregates Induced Green Emission of Biocompatible Citric Acid-PEG Hyper Branched Polymer

Abstract

An aliphatic citric acid-PEG hyper-branched polymer (CPHP) with a π-bond on the polymer backbone was synthesized by a single-step melt reaction in which the polymerization and π-bond formation occur simultaneously. The chemical structure of CPHP was confirmed by FTIR, 1H-NMR, 13C-NMR and MALDI-TOF mass spectral analyses. Aggregates are generally found to disperse in any solvent but the CPHP aggregates were soluble in water due to their hybrid nature. The π-bond in the aconitate unit induces green emission by CH/π interaction while the PEG unit of CPHP increases its solubility in water. The soluble aggregates induced green emission (SAIE) of the CPHP was investigated by UV-Visible absorption and emission spectra, time-correlated single photon counting (TCSPC) and zeta potential measurements. The fluorescence life time (τf) increased from 4.93 to11.38 ns with an increase in CPHP concentration. The fluorescence quantum yield (Φf) of CPHP can be altered by varying the concentration of CPHP.