Investigation of phase transformations and corrosion resistance in Co/CoCo2O4 nanowires and their potential use as a basis for lithium-ion batteries

Abstract

The paper is devoted to the study of the effect of thermal annealing on the change in the structural properties and phase composition of metal Co nanostructures, as well as the prospects of their use as anode materials for lithium-ion batteries. During the study, a four-stage phase transition in the structure of nanowires consisting of successive transformations of the structure (Со-FCC/Co-HCP) → (Со-FCС) → (Со-FCC/СоСо2О4) → (СоСо2О4), accompanied by uniform oxidation of the structure of nanowires with an increase in temperature above 400 °C. In this case, an increase in temperature to 700 °C leads to a partial destruction of the oxide layer and surface degradation of nanostructures. During life tests, it was found that the lifetime for oxide nanostructures exceeds 500 charge/discharge cycles, for the initial nanostructures and annealed at a temperature of 300 °С, the lifetimes are 297 and 411 cycles, respectively. The prospects of using Co/CoCo2O4 nanowires as the basis for lithium-ion batteries is shown.