Ti(Phen)(OC2H5)2Cl2: A highly efficient pre-catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide

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Abstract

A newly developed and structurally characterized titanium complex [Ti(Phen)(OC2H5)2Cl2] (Phen = 1,10-phenanthroline) is reported as a homogeneous pre-catalyst for the selective oxidation of organic sulfides to sulfoxides with a stoichiometric amount of 30% aq. H2O2 in CH3OH at room temperature. This catalytic system showed high yield (95-100%) and good selectivity (92-100%) during the catalytic reaction in a short period of time.

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Wu, R. H., Wu, J., Yu, M. X., & Zhu, L. G. (2017). Ti(Phen)(OC2H5)2Cl2: A highly efficient pre-catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide. RSC Advances, 7(70), 44259–44264. https://doi.org/10.1039/c7ra06883b

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