[N,N′-Bis(2,6-diisopropylphenyl)pentane- 2,4-diamine(1)- 2κ2 N,N′]-μ2-chlorido-1: 2κ2 Cl:Cl-chlorido-2κCl-bis-(1,2-di-methoxyethane- 1κ2 O,O′)iron(II)lithium

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Abstract

In the title compound, [FeLi(C29H41N 2)Cl2(C4H10O2) 2], the FeII atom is coordinated by two N and two Cl atoms, generating a distorted FeN2Cl2 tetra-hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy-ethane mol-ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å.

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Grubba, R., Ponikiewski, Ł., Tomorowicz, Ł., & Pikies, J. (2010). [N,N′-Bis(2,6-diisopropylphenyl)pentane- 2,4-diamine(1)- 2κ2 N,N′]-μ2-chlorido-1: 2κ2 Cl:Cl-chlorido-2κCl-bis-(1,2-di-methoxyethane- 1κ2 O,O′)iron(II)lithium. Acta Crystallographica Section E: Structure Reports Online, 66(6). https://doi.org/10.1107/S1600536810018222

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