Abstract
The solubility of oxygen in molten Ti-Al and Zr-Al alloys equilibrated with solid Al2O3 or ZrO2 was measured from 1673 to 1973 K. The standard Gibbs energies for the reactions of Al2O3(s) = 2Al (1, in Ti-Al alloy)+30 (mass pct, in Ti-Al alloy) and ZrO2(s) = Zr (1, in Zr-Al alloy)+2O (mass pct, in Zr-Al alloy) were determined as a function of temperature. The standard Gibbs energies of the dissolution of oxygen into molten titanium and zirconium were obtained by applying the regular solution model to the Ti-Al-O and Zr-Al-O systems.
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CITATION STYLE
Kobayashi, Y., & Tsukihashi, F. (2000). Thermodynamics of oxygen in molten Ti-Al and Zr-Al alloys. High Temperature Materials and Processes, 19(3), 211–217. https://doi.org/10.1515/HTMP.2000.19.3-4.211
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