Synthesis and electrochemistry of phthalocyanines bearing [(3,4-dimethoxybenzyl)oxy] groups

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Abstract

In this study peripherally tetra-substituted metal-free, metallophthalocyanines bearing (3,4-dimethoxybenzyl) oxy groups have been synthesized and characterized. Electrochemical properties of novel phthalocyanines 4, 5, 6, and 7 were determined by cyclic and square wave voltammetry in order to define their possible applications in different electrochemical technologies. Co II and Ti IV O metal ions behave as redox active cations in the core of the CoPc and TiOPc complexes, respectively. Voltammetric studies revealed that phthalocyanines have reversible/irreversible redox processes, which are the main requirement for the technological usage of these compounds.

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Ömeroʇlu, I., & Biyiklioʇlu, Z. (2015). Synthesis and electrochemistry of phthalocyanines bearing [(3,4-dimethoxybenzyl)oxy] groups. Turkish Journal of Chemistry, 39(2), 347–358. https://doi.org/10.3906/kim-1408-71

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