Mechanistic investigations of the asymmetric hydrosilylation of ketimines with trichlorosilane reveals a dual activation model and an organocatalyst with enhanced efficiency

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Abstract

Structural probes used to help elucidate mechanistic information of the organocatalyzed asymmetric ketimine hydrosilylation have revealed a new catalyst with unprecedented catalytic activity, maintaining adequate performance at 0.01 mol% loading. A new ‘dual activation’ model has been proposed that relies on the presence of both a Lewis basic and Brønsted acidic site within the catalyst architecture.

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Li, X., Reeder, A. T., Torri, F., Adams, H., & Jones, S. (2017). Mechanistic investigations of the asymmetric hydrosilylation of ketimines with trichlorosilane reveals a dual activation model and an organocatalyst with enhanced efficiency. Organic and Biomolecular Chemistry, 15(11), 2422–2435. https://doi.org/10.1039/c6ob02537d

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