Gel free polymerization of N, N′-methylenebisacrylamide initiated by a peroxodiphosphate-thioacetamide redox system. A kinetic study

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Abstract

The kinetics of polymerization of the divinyl monomer, i.e., N, N′-methylenebisacrylamide has been studied employing a peroxodiphosphate-thioacetamide redox system under inert atmosphere at 40±1°C. The rate of polymerization Rp, was proportional to [Monomer]1, [Thioacetamide]1.0, and [Peroxodiophosphate]0.5. Based on the experimental results, cyclopolymerization of the growing radicals and mutual termination has been proposed. © 1993, The Society of Polymer Science, Japan. All rights reserved.

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Behari, K., Agrawal, U., & Das, R. (1993). Gel free polymerization of N, N′-methylenebisacrylamide initiated by a peroxodiphosphate-thioacetamide redox system. A kinetic study. Polymer Journal, 25(10), 1007–1013. https://doi.org/10.1295/polymj.25.1007

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