A stratospheric intrusion-influenced ozone pollution episode associated with an intense horizontal-trough event

Abstract

Ozone pollution is currently a serious issue in China. As an important source of tropospheric ozone, the stratospheric ozone has received less concern. This study uses a combination of ground-based ozone measurements, the latest ERA5 reanalysis data as well as chemistry-climate model and Lagrangian Particle Dispersion Modeling (LPDM) simulations to investigate the potential impacts of stratospheric intrusion (SI) on surface ozone pollution episodes in eastern China. Station-based observations indicate that severe ozone pollution occurred from 27 April to 28 April 2018 in eastern China, with maximal values over 140 ppbv. ERA5 meteorological and ozone data suggest that a strong horizontal-trough exists at the same time, which leads to an evident SI event and brings ozone-rich air from the stratosphere to the troposphere. Using a stratospheric ozone tracer defined by NCAR's Community Atmosphere Model with Chemistry (CAM-Chem), we conclude that this SI event contributed about 15 ppbv (15%) to the surface ozone pollution episode during 27-28 April in eastern China. The potential impacts of SI events on surface ozone variations should be therefore considered in ozone forecast and control.