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Phase-transfer-catalyzed asymmetric synthesis of 1,1-disubstituted tetrahydroisoquinolines

Advanced Synthesis and Catalysis (2011) 353(14-15) 2614-2618
DOI: 10.1002/adsc.201100269
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Abstract

A highly efficient catalytic asymmetric synthesis of 1,1-disubstituted tetrahydroisoquinolines has been achieved via asymmetric alkylation or Michael addition of 1-cyanotetrahydroisoquinolines using binaphthyl-modified N-spiro-type chiral phase-transfer catalysts. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Shirakawa, S., Liu, K., Ito, H., Le, T. N., & Maruoka, K. (2011). Phase-transfer-catalyzed asymmetric synthesis of 1,1-disubstituted tetrahydroisoquinolines. Advanced Synthesis and Catalysis, 353(14–15), 2614–2618. https://doi.org/10.1002/adsc.201100269

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