The reaction of 4,5-dicyano-2-methoxyimidazole (L1) with Co(NO3)2·6H2O under solvothermal conditions in DMF, a MOF, IFP-8 and a hydrogen-bonded network consisting of tetradecanuclear Co(ii)14-metal organic cube (1) are achieved. 1 shows the bcu net with 14 cobalt atoms. © 2014 Partner Organisations.
CITATION STYLE
Sekhar Mondal, S., Bhunia, A., Kelling, A., Schilde, U., Janiak, C., & Holdt, H. J. (2014). A supramolecular Co(ii)14-metal-organic cube in a hydrogen-bonded network and a Co(ii)-organic framework with a flexible methoxy substituent. Chemical Communications, 50(41), 5441–5443. https://doi.org/10.1039/c3cc49698h
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