Bismuth nitrate-induced microwave-assisted expeditious synthesis of vanillin from curcumin

Abstract

BACKGROUND: Curcumin and vanillin are the two useful compounds in food and medicine. Bismuth nitrate pentahydrate is an economical and ecofriendly reagent. METHOD: Bismuth nitrate pentahydrate impregnated montmorillonite KSF clay and curcumin were subjected to microwave irradiation. RESULTS: Microwave-induced bismuth nitrate-promoted synthesis of vanillin from curcumin has been accomplished in good yield under solvent-free condition. Twenty-five different reaction conditions have been studied to optimize the process. CONCLUSION: The present procedure for the synthesis of vanillin may find useful application in the area of industrial process development.