Abstract
The great escape! In the transition of (Me2S)B9H13 into (RH2N)B8H11NHR, one boron atom is lost. Boron-substituted derivatives of (Me2S)B9H13 were used to identify this boron atom, which turned out to be firmly integrated in the starting cluster (see scheme). A pathway for the conversion is proposed.
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APA
El-Zaria, M. E., Dörfler, U., Hofmann, M., & Gabel, D. (2002). Conversion of arachno-nonaborane into azanonaborane: Unexpected loss of a firmly integrated boron atom. Angewandte Chemie - International Edition, 41(23), 4498–4500. https://doi.org/10.1002/1521-3773(20021202)41:23<4498::AID-ANIE4498>3.0.CO;2-0
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