Benzyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate

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Abstract

The title compound, C17H16N2S2, a dithio-carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl-idine group. The 3-phenyl-prop-2-enyl-idene and dithio-carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenyl-prop-2-enyl-idene and the benzyl group is 77.78 (7)°. In the crystal structure, mol-ecules are linked by an N - H⋯S hydrogen bond and a weak C - H⋯S inter-action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C - H⋯π inter-actions.

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Tarafder, M. T. H., Crouse, K. A., Islam, M. T., Chantrapromma, S., & Fun, H. K. (2008). Benzyl 3-[(E,E)-3-phenyl-prop-2-enyl-idene]dithio-carbazate. Acta Crystallographica Section E: Structure Reports Online, 64(6). https://doi.org/10.1107/S1600536808013354

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