A hexameric [Mn III 18 Na6] wheel based on [Mn III 3 O]7+ sub-units

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Abstract

A novel hexameric [MnIII18Na6] wheel-like aggregate consisting of [MnIII3O] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [MnIII3O] triangles, and the only one with a wheel-like metal topology.

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Manoli, M., Inglis, R., Piligkos, S., Yanhua, L., Wernsdorfer, W., Brechin, E. K., & Tasiopoulos, A. J. (2016). A hexameric [Mn III 18 Na6] wheel based on [Mn III 3 O]7+ sub-units. Chemical Communications, 52(87), 12829–12832. https://doi.org/10.1039/c6cc06644e

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