Synthesis, structure, morphology, and luminescent properties of Ba2MgWO6: Eu3+ double perovskite obtained by a novel co-precipitation method

Abstract

Eu3+ doped Ba2MgWO6 (BMW) double-perovskite was successfully synthesized for the first time by the co-precipitation method. The synthesis procedure, crystal structure, as well as morphology of obtained samples are presented. Domination of the 5D0-7F1 magnetic-dipole over forced electric-dipole transitions in the emission spectra indicates that Eu3+ ions are located in the high symmetry site with inversion center. Only one emission line assigned to the 5D0-7F0 transition was observed, confirming that europium substituted for only one host cation site. The photoluminescence excitation (PLE) spectrum is dominated by a strong and broad band related to the O2- →Eu3+ and O2- →W6+ charge transfer. The decay of the emission from the 5D0 and 5D1 levels was investigated. The temperature-dependent emission spectra showed that the T0.5 is equal to 350 K. Extinguishing mechanisms of the Eu3+ luminescence in the studied host are discussed.