Abstract
Three complexes [Co(2-XPy)2Cl2] (X = Cl, Br, and I) were prepared and characterized, representing a rare case of isostructurality within the Cl-Br-I row. The nature of halogen bonding (XB) in a solid state was studied by DFT calculations, revealing a tendency of XB energy growth for heavier halogens.
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Adonin, S. A., Bondarenko, M. A., Novikov, A. S., & Sokolov, M. N. (2020). Halogen bonding in isostructural Co(II) complexes with 2-halopyridines. Crystals, 10(4). https://doi.org/10.3390/cryst10040289
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