Thermodynamic property study of nanostructured Mg-H, Mg-Ni-H, and Mg-Cu-H systems by high pressure DSC method

Abstract

Mg, Ni, and Cu nanoparticles were synthesized by hydrogen plasma metal reaction method. Preparation of Mg2Ni and Mg2Cu alloys from these Mg, Ni, and Cu nanoparticles has been successfully achieved in convenient conditions. High pressure differential scanning calorimetry (DSC) technique in hydrogen atmosphere was applied to study the synthesis and thermodynamic properties of the hydrogen absorption/desorption processes of nanostructured Mg-H, Mg-Ni-H, and Mg-Cu-H systems. Van't Hoff equation of Mg-Ni-H system as well as formation enthalpy and entropy of Mg 2NiH4 was obtained by high pressure DSC method. The results agree with the ones by pressure-composition isotherm (PCT) methods in our previous work and the ones in literature. Copyright © 2013 Huaiyu Shao et al.