The first amino acid bound manganese-calcium clusters: A {[Mn III 3 Ca]2} methylalanine complex, and a [Mn III 6 Ca] trigonal prism

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Abstract

An amino acid containing octanuclear heterometallic {[MnIII3Ca]2} cluster has been synthesized, alongside a structurally-related trigonal prismatic [MnIII6Ca]2+ cage.

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Tziotzi, T. G., Andreou, E. K., Tzanetou, E., Kalofolias, D. A., Cutler, D. J., Weselski, M., … Milios, C. J. (2020). The first amino acid bound manganese-calcium clusters: A {[Mn III 3 Ca]2} methylalanine complex, and a [Mn III 6 Ca] trigonal prism. Dalton Transactions, 49(30), 10339–10343. https://doi.org/10.1039/d0dt01916j

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