(5S)-5-[(4aR,8aS,9E,11S,13R,14S,16R,17R,19S)-11,19-dihydroxy-8,10,13,16-tetramethyl-18-methylidene-3,4,5,6,8a,11,12,13,14,15,16,17,18,19,20,21-hexadecahydro-2H-14,17-epoxybenzo[2,3]cyclohexadeca[1,2-b]pyridine-7-yl]-3-methylfuran-2(5H)-one (12-methylgymnodimine B)

Wendy Strangman; Matthew Anttila; Carmelo Tomas; Jeffrey L.C. Wright

Journal ArticleOPEN ACCESS

(5S)-5-[(4aR,8aS,9E,11S,13R,14S,16R,17R,19S)-11,19-dihydroxy-8,10,13,16-tetramethyl-18-methylidene-3,4,5,6,8a,11,12,13,14,15,16,17,18,19,20,21-hexadecahydro-2H-14,17-epoxybenzo[2,3]cyclohexadeca[1,2-b]pyridine-7-yl]-3-methylfuran-2(5H)-one (12-methylgymnodimine B)

MolBank (2016) 2016(2)

DOI: 10.3390/M896

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Abstract

A new member of the gymnodimine class of spiroimine toxins has been isolated from a laboratory culture strain of Alexandrium ostenfeldii. Extensive one-dimensional (1D) and two-dimensional (2D) NMR data analysis was used to elucidate its structure as 12-methylgymnodimine B.

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Strangman, W., Anttila, M., Tomas, C., & Wright, J. L. C. (2016). (5S)-5-[(4aR,8aS,9E,11S,13R,14S,16R,17R,19S)-11,19-dihydroxy-8,10,13,16-tetramethyl-18-methylidene-3,4,5,6,8a,11,12,13,14,15,16,17,18,19,20,21-hexadecahydro-2H-14,17-epoxybenzo[2,3]cyclohexadeca[1,2-b]pyridine-7-yl]-3-methylfuran-2(5H)-one (12-methylgymnodimine B). MolBank, 2016(2). https://doi.org/10.3390/M896

(5S)-5-[(4aR,8aS,9E,11S,13R,14S,16R,17R,19S)-11,19-dihydroxy-8,10,13,16-tetramethyl-18-methylidene-3,4,5,6,8a,11,12,13,14,15,16,17,18,19,20,21-hexadecahydro-2H-14,17-epoxybenzo[2,3]cyclohexadeca[1,2-b]pyridine-7-yl]-3-methylfuran-2(5H)-one (12-methylgymnodimine B)

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