Catalytic constructive deoxygenation of lignin-derived phenols: New C-C bond formation processes from imidazole-sulfonates and ether cleavage reactions

Abstract

As part of a programme aimed at exploiting lignin as a chemical feedstock for less oxygenated fine chemicals, several catalytic C-C bond forming reactions utilising guaiacol imidazole sulfonate are demonstrated. These include the cross-coupling of a Grignard, a non-toxic cyanide source, a benzoxazole, and nitromethane. A modified Meyers reaction is used to accomplish a second constructive deoxygenation on a benzoxazole functionalised anisole. © Partner Organisations 2014.