Fully hydrated as well as dried benzaldehyde complexes of α- and β-cyclodextrins were studied by using CP/MAS13C NMR techniques. Variable temperature studies have shown that below ∼ 200 K the guest is rigidly held in the complex, whereas at 328 K, only the aromatic ring performs rapid two-fold flips about the C1-C4 axis. In the β-Cd complex the benzaldehyde performs more general reorientation. Removal of water causes marked changes in both guest and host spectra, generally consistent with a loss of short-range order and increase in guest motional rate. © 1988 National Research Council of Canada.
CITATION STYLE
Ripmeester, J. A. (1988). Variable temperature CP/MAS13C NMR study of cyclodextrin complexes of benzaldehyde. Journal of Inclusion Phenomena, 6(1), 31–40. https://doi.org/10.1007/BF00659366
Mendeley helps you to discover research relevant for your work.