Abstract
(Chemical Equation Presented) Ringing the changes: Iridium(lll)-salen complexes 1 bearing a σ-coordinated aryl ligand (L = CH3C 6H4, C6H5) at the apical position are found to efficiently catalyze the cis- and enantioselective cyclopropanation of mono- and disubstituted olefins (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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Kanchiku, S., Suematsu, H., Matsumoto, K., Uchida, T., & Katsuki, T. (2007). Construction of an aryliridium-salen complex for highly cis- and enantioselective cyclopropanations. Angewandte Chemie - International Edition, 46(21), 3889–3891. https://doi.org/10.1002/anie.200604385
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