The magnetic properties (magnetic ordering temperature and magnetization) of the ferrimagnetic compounds R2 Fe14B (R = Gd, Tb, Dy, Ho and Er) and their hydrides R2Fe14BH2.5 were studied. It was found that incorporation of hydrogen into the crystal lattice of R2 Fe14B compounds substantially increases the Curie temperature and Fe-Fe exchange interactions. Hydrogenation does not practically change the intersublattice exchange field h21 and exchange field h22 within the R - sublattice. This effect can be understood as a result of the attendant changes in the unit cell volume and an electronic structure of these compounds. © 2007 Springer.
CITATION STYLE
Tereshina, I. S., Chistyakov, O. D., Burkhanov, G. S., Tereshina, E. A., Nikitin, S. A., Folcik, L., & Drulis, H. (2007). Change of curie temperature and effective exchange fields in ferrimagnetic R2Fe14B compounds upon hydrogenation. In NATO Security through Science Series A: Chemistry and Biology (pp. 599–604). https://doi.org/10.1007/978-1-4020-5514-0_76
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