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Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework

  • Godfrey H
  • da Silva I
  • Briggs L
  • et al.
Angewandte Chemie (2018) 130(45) 14994-14997
DOI: 10.1002/ange.201808316
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Abstract

MFM‐300(Al) shows reversible uptake of NH 3 (15.7 mmol g −1 at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm −3 at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro‐spectroscopy on ND 3 @MFM‐300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction.

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Godfrey, H. G. W., da Silva, I., Briggs, L., Carter, J. H., Morris, C. G., Savage, M., … Schröder, M. (2018). Ammonia Storage by Reversible Host–Guest Site Exchange in a Robust Metal–Organic Framework. Angewandte Chemie, 130(45), 14994–14997. https://doi.org/10.1002/ange.201808316

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